Not necessarily. In order for you to establish that medical malpractice has occurred, it must be proven that the physician who amputated your foot deviated from the accepted standard of care. Just because your wife’s friend would not have amputated does not mean the physician deviated from the standard of care. To have a case, you need to prove that no reasonable physician in that specialty would have amputated.
As each case is unique, consult a lawyer if you wish to discuss the specifics of your case.